Structural Studies On Coal Using Solid-state Nmr and Mass-spectrometry .1. Selective Cleavage of Ether Linkages
(1991) Fuel : the science and technology of fuel and energy — Vol. 70, n° 5, p. 627-633 (1991)
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- Abstract
- The ether linkages in coal were selectively cleaved by a reagent SiCl4/NaI. The soluble products obtained after the degradation were fractionated and characterized by gas chromatography-mass spectrometry (g.c.-m.s.) and chemical ionization m.s. (c.i.m.s.). Structural changes in the original coal and the residue obtained after degradation were studied by C-13 cross polarization, magic angle spinning n.m.r. (CP/MAS n.m.r.). The results of the analysis of the soluble products supported the findings of solid state n.m.r. studies.
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Prasad, JV., Das, KG., & Dereppe, J.-M. (1991). Structural Studies On Coal Using Solid-state Nmr and Mass-spectrometry .1. Selective Cleavage of Ether Linkages. Fuel : the science and technology of fuel and energy, 70(5), 627-633. https://doi.org/10.1016/0016-2361(91)90177-C (Original work published 1991)