Synthesis and Crystal-structure of Chlorotriphenyl-1-[(4'-methoxyphenylimino)-methyl]-2-naphtholtin(iv)
Teoh, SG.;Teo, SB.;Yeap, GY.;Declercq, Jean-Paul
(1992) Journal of Coordination Chemistry — Vol. 25, n° 4, p. 327-333 (1992)
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Authors
Teoh, SG.
Author
Teo, SB.
Author
Yeap, GY.
Author
Declercq, Jean-PaulUCLouvain
Author
Abstract
The adduct derived from the reaction of 1-[(4'-methoxyphenylimino)-methyl]-2-naphthol with triphenyltin(IV) chloride, and which exhibits 1 : 1 stoichiometry (ligand: organotin), has been characterized spectroscopically and by an X-ray structural analysis. The complex possesses trigonal bipyramidal geometry around the Sn atom with the three phenyl rings in equatorial positions; coordination of the ligand to the metal occurs via the phenolic oxygen atom.