Synthesis and Crystal-structure of Chlorotriphenyl-1-[(4'-methoxyphenylimino)-methyl]-2-naphtholtin(iv)

Teoh, SG.;Teo, SB.;Yeap, GY.;Declercq, Jean-Paul
(1992) Journal of Coordination Chemistry — Vol. 25, n° 4, p. 327-333 (1992)

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  • Teoh, SG.
    Author
  • Teo, SB.
    Author
  • Yeap, GY.
    Author
  • Declercq, Jean-PaulUCLouvain
    Author
Abstract
The adduct derived from the reaction of 1-[(4'-methoxyphenylimino)-methyl]-2-naphthol with triphenyltin(IV) chloride, and which exhibits 1 : 1 stoichiometry (ligand: organotin), has been characterized spectroscopically and by an X-ray structural analysis. The complex possesses trigonal bipyramidal geometry around the Sn atom with the three phenyl rings in equatorial positions; coordination of the ligand to the metal occurs via the phenolic oxygen atom.
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Teoh, SG., Teo, SB., Yeap, GY., & Declercq, J.-P. (1992). Synthesis and Crystal-structure of Chlorotriphenyl-1-[(4′-methoxyphenylimino)-methyl]-2-naphtholtin(iv). Journal of Coordination Chemistry, 25(4), 327-333. https://doi.org/10.1080/00958979209409206 (Original work published 1992)