New acylnitroso compounds for the asymmetric oxyamination of dienes

Gouverneur, Veronique;McCarthy, SJ;Mineur, C.;Belotti, D;Ghosez, Léon;et.al.
(1998) Tetrahedron — Vol. 54, n° 35, p. 10537-10554 (1998)

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Authors
  • Gouverneur, Veronique
    Author
  • McCarthy, SJ
    Author
  • Mineur, C.
    Author
  • Belotti, D
    Author
  • Ghosez, LéonUCLouvain
    Author
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Abstract
A series of new enantiomerically pure acylnitroso compounds have been prepared and tested as dienophiles for the asymmetric oxyamination of dienes. Very high selectivities were obtained with acylnitroso compounds derived from diphenylmethoxymethyl pyrrolidine 2c, the C-2-symmetric pyrrolidines 2d-e and camphorsultam 2f. (C) 1998 Elsevier Science Ltd. All rights reserved.
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Citations

Gouverneur, V., McCarthy, S., Mineur, C., Belotti, D., Dive, G., & Ghosez, L. (1998). New acylnitroso compounds for the asymmetric oxyamination of dienes. Tetrahedron, 54(35), 10537-10554. https://doi.org/10.1016/S0040-4020(98)00504-3 (Original work published 1998)