Supramolecular homochiral helicity and zigzag hydrogen bonded chains in 1,2,4-triazole derived aminoester and aminoacid

Dîrtu, Marinela;Adarsh, N. N.;Naik, Anil;Robeyns, Koen;Garcia, Yann
(2016) New Journal of Chemistry — Vol. 40, p. 9025-9029 (2016)

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Authors
  • Dîrtu, MarinelaUCLouvain
    Author
  • Adarsh, N. N.UCLouvain
    Author
  • Naik, AnilUCLouvain
    Author
  • Robeyns, KoenUCLouvain
    Author
  • Garcia, Yannorcid-logoUCLouvain
    Author
Abstract
Two precursors for coordination polymer design, namely ethyl-4H-1,2,4-triazol-4-yl-acetate (1) and 4-(4H-1,2,4-triazol-4-yl)L-propionic acid (2), were prepared via a transamination reaction followed by crystallization from MeOH. Single crystal X-ray data analysis revealed that 1 and 2 exhibit homochiral helical and 2D hydrogen bonded networks, respectively.
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Dîrtu, M., Adarsh, N. N., Naik, A., Robeyns, K., & Garcia, Y. (2016). Supramolecular homochiral helicity and zigzag hydrogen bonded chains in 1,2,4-triazole derived aminoester and aminoacid. New Journal of Chemistry, 40, 9025-9029. https://doi.org/10.1039/c6nj01687a (Original work published 2016)