Influence of the coordination mode in [Ni{RC(S)NP(S)(OiPr)2)2] for the formation of nickel-containing nanoparticles
(2012) Dalton Transactions — Vol. 41, n° 8, p. 2234-2236 (2012)
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- The complex [Ni{2-PyNHC(S)NP(S)(OiPr) 2-1,5,7-N,N′,S} 2] ([NiL I 2]) dissolved in tri-n-octylphosphine (TOP) is decomposed in hot hexadecylamine (HDA) to give TOP-capped Ni nanoparticles. The same procedure using [Ni{2-MeC 6H 4NHC(S)NP(S)(OiPr) 2} 2-1,3-N,S] ([NiL II 2]) and [Ni{PhC(S)NP(S)(OiPr) 2-1,5-S, S′} 2] ([NiL III 2]) leads to the formation of NiS nanoparticles with the rhombohedral and hexagonal structures, respectively. NiH x nanoparticles were also produced from a mixture of [NiL I 2] and N 2H 4. The obtained Ni nanoparticles can be used for the catalytic addition of Ph 2S 2 to 1-, 2- and 3-hexynes. © The Royal Society of Chemistry 2012.
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Babashkina, M. G., Safin, D., & Garcia, Y. (2012). Influence of the coordination mode in [Ni{RC(S)NP(S)(OiPr)2)2] for the formation of nickel-containing nanoparticles. Dalton Transactions, 41(8), 2234-2236. https://doi.org/10.1039/c1dt11755f (Original work published 2012)