Dramatic effect of PSE clamping on the behaviour of d-glucal under Ferrier I conditions

Fernandes, Antony;Dell'Olmo, Maxime;Tatibouët, Arnaud;Imberty, Anne;Rollin, Patrick;et.al.
(2008) Tetrahedron Letters — Vol. 49, n° 21, p. 3484-3488 (2008)

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Authors
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  • Dell'Olmo, MaximeUniversité d’Orléans
    Author
  • Tatibouët, ArnaudUniversité d’Orléans
    Author
  • Imberty, AnneUniversité Joseph Fourier, Grenoble, France
    Author
  • Rollin, PatrickUniversité d’Orléans
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Abstract
Clamped by the acid-resistant phenylsulfonylethylidene (PSE) acetal, d-glucal privileged the additive pathway over the Ferrier I rearrangement when confronted with protic nucleophiles.
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Citations

Fernandes, A., Dell’Olmo, M., Tatibouët, A., Imberty, A., Philouze, C., & Rollin, P. (2008). Dramatic effect of PSE clamping on the behaviour of d-glucal under Ferrier I conditions. Tetrahedron Letters, 49(21), 3484-3488. https://doi.org/10.1016/j.tetlet.2008.03.093 (Original work published 2008)