Halomethyl-cobalt(bis-acetylacetonate) for the controlled synthesis of functional polymers
(2015) Chemical Communications — Vol. 51, n° 76, p. 14334-14337 (2015)
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- Abstract
- Novel organocobalt complexes featuring weak C–CoL2 bonds (L = acetylacetonate) are prepared and used as sources of halomethyl radicals. They permit the precision synthesis of a-halide functionalized and telechelic polymers in organic media or in water. Substitution of halide by azide allows derivatization of polymers using the CuAAC click reaction.
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Demarteau, J., Kermagoret, A., German, I., Cordella, D., Robeyns, K., De Winter, J., Gerbaux, P., Jerôme, C., Debuigne, A., & Detrembleur, C. (2015). Halomethyl-cobalt(bis-acetylacetonate) for the controlled synthesis of functional polymers. Chemical Communications, 51(76), 14334-14337. https://doi.org/10.1039/c5cc04714e (Original work published 2015)