New efficient copper fluoride-based catalyst for enantioselective hydrosilylation of ketones in aerobic conditions

Courmarcel, J;Mostefai, Naouël;Sirol, S;Choppin, S;Riant, Olivier
(2001) Israel Journal of Chemistry — Vol. 41, n° 4, p. 231-240 (2001)

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  • Courmarcel, J
    Author
  • Mostefai, NaouëlUCLouvain
    Author
  • Sirol, S
    Author
  • Choppin, S
    Author
  • Riant, OlivierUCLouvain
    Author
Abstract
A new copper(II) fluoride-chiral diphosphines catalytic system was developed. This one is very efficient and selective for the hydrosilylation of several substituted or unsubstituted aromatic ketones in so far as moderate to excellent enantioselectivities were obtained. An oxygen acceleration effect was observed that led us to propose a practical protocol with a low amount of catalyst.
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Courmarcel, J., Mostefai, N., Sirol, S., Choppin, S., & Riant, O. (2001). New efficient copper fluoride-based catalyst for enantioselective hydrosilylation of ketones in aerobic conditions. Israel Journal of Chemistry, 41(4), 231-240. https://doi.org/10.1560/ARBM-9XXY-7GVB-XU5B (Original work published 2001)