Fe(II) spin transition including an amino-ester 1,2,4-triazole derivative, operating at, below and above room temperature
(2016) Inorganic Chemistry — Vol. 55, n° 9, p. 4278-4295 (2016)
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- Abstract
- [Fe(αEtGlytrz)3](NO3)2 displays a hysteresis loop of 60 K width, centered at room temperature along with a thermochromic effect. Such bistability domain is the widest for Fe(II) chains with 4R-1,2,4-triazole as ligands. Structure−properties relationships are discussed for this new family of spin-crossover chains with the ethyl-4H-1,2,4-triazol-4-yl-acetate (αEtGlytrz) ligand.
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DÎrtu, M. M., Naik, A., Rotaru, A., Spinu, L., Poelman, D., & Garcia, Y. (2016). Fe(II) spin transition including an amino-ester 1,2,4-triazole derivative, operating at, below and above room temperature. Inorganic Chemistry, 55(9), 4278-4295. https://doi.org/10.1021/acs.inorgchem.6b00015 (Original work published 2016)