[Analysis of Final Products From the Liquid Alkanes Radiolysis At Low-dose, Low-temperature and High-dose Rate]
(1991) Journal de Chimie Physique — Vol. 88, n° 6, p. 1195-1207 (1991)
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- Abstract
- Yields of final products (dimers) from the radiolysis of n-hexane and 2,3-dimethylbutane are studied by capillary chromatographic techniques for trace analysis. Reaction of intermediates with the products, the alkane molecules or impurities, is reduced by using low dose (1 kGy), low temperature (195 K) and high dose rate (LINAC). Temperature is the most important experiment variable; by reducing the temperature, reactions with significant activation energies do not compete with radical-radical termination reactions. Products from LINAC radiolysis provide information about active species (reactive fragment, allylic radical...) which deserve a more detailed examination by direct methods.
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Tilquin, B., & Dedoncker, J. (1991). [Analysis of Final Products From the Liquid Alkanes Radiolysis At Low-dose, Low-temperature and High-dose Rate]. Journal de Chimie Physique, 88(6), 1195-1207. https://hdl.handle.net/2078.5/42215 (Original work published 1991)