Novel low-temperature synthesis of titanium nitride: proposal for cyanonitridation mechanism

Clement, F;Bastians, P.;Grange, Paul
(1997) XIIIth International Symposium on the Reactivity of Solids — Location: HAMBURG(Germany) (8.September.1996)

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  • Clement, F
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  • Bastians, P.
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  • Grange, PaulUCLouvain
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Abstract
Low temperature nitridation of titanium dioxide using monomethylamine as a reactant is obtained. The first reaction is the decomposition of monomethylamine into HCN and atomic hydrogen. The second step is the partial reduction of titanium dioxide. The third step is the nitridation of the TiO by HCN.
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Clement, F., Bastians, P., & Grange, P. (1997). Novel low-temperature synthesis of titanium nitride: proposal for cyanonitridation mechanism. Solid State Ionics, 101, 171-174. https://hdl.handle.net/2078.5/87429 (Original work published 1997)