Deformation of the Adamantane Skeleton By Substitution - Crystal-structure of 1-methylsulfonyladamantane
(1993) Collection of Czechoslovak Chemical Communications — Vol. 58, n° 2, p. 373-377 (1993)
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- Abstract
- The crystals of 1-methylsulfonyladamantane are monoclinic, space group P2(1)/a, with a = 11.094(3), b = 7.668(2). c = 13.161(3) angstrom, beta = 101.74(2)0 , V = 1 096.1(5) angstrom3, Z = 4, D(x) = 1.29 g cm-3, MoKalpha, lambda = 0.71069 angstrom, mu = 2.65 cm-1, F(000) = 456, T = 291 K, the final R value is 0.036 for 1 834 observed reflections. For this compound and from literature data, the bond angles of adamantane derivatives are briefly discussed: the angle on the substituted C(1) atom depends clearly on the substituent but the available figures are still rather imprecise.
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Tinant, B., Declercq, J.-P., & Exner, O. (1993). Deformation of the Adamantane Skeleton By Substitution - Crystal-structure of 1-methylsulfonyladamantane. Collection of Czechoslovak Chemical Communications, 58(2), 373-377. https://doi.org/10.1135/cccc19930373 (Original work published 1993)