Asymmetric Synthesis of a Chiral Tetradendate Ligand Based on a Bis[diphenylphosphino-ferrocenyl] Moiety. Electrochemical Behaviour of Free Ligand and its RuII and CuI Complexes

Masson-Szymczak, Anne;Riant, Olivier;Gref, Aurore;Kagan, Henri B.
(1996) Journal of Organometallic Chemistry — Vol. 511, n° 1-2, p. 193-197 (1996)

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Authors
  • Masson-Szymczak, Anne
    Author
  • Riant, OlivierUCLouvain
    Author
  • Gref, Aurore-
    Author
  • Kagan, Henri B.
    Author
Abstract
α-Diphenylphosphino carboxaldehyde 4, prepared by asymmetric synthesis, was reacted with ethane diamine to give bisimine bisphosphine 5. Ruthenium(II) complex 6 and copper(I) complex 8 were easily formed and their electrochemical properties studied.
Affiliations
  • Université Paris-Sud (France)Chimie organique

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Masson-Szymczak, A., Riant, O., Gref, A., & Kagan, H. B. (1996). Asymmetric Synthesis of a Chiral Tetradendate Ligand Based on a Bis[diphenylphosphino-ferrocenyl] Moiety. Electrochemical Behaviour of Free Ligand and its RuII and CuI Complexes. Journal of Organometallic Chemistry, 511(1-2), 193-197. https://doi.org/10.1016/0022-328X(95)05968-U (Original work published 1996)