Synthetic Studies Towards Milbemycin Beta(3) - Rapid Construction of a Model Spiroketal Subunit Using the Intramolecular Silyl Modified Sakurai (isms) Methodology

Marko, Istvan;Declercq, Jean-Paul;Bailey, M.;Murphy, F.;Dumont, W.;et.al.
(1995) Synlett : accounts and rapid communications in synthetic organic chemistry — n° 1, p. 123-126 (1995)

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  • Marko, IstvanUCLouvain
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  • Declercq, Jean-PaulUCLouvain
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  • Bailey, M.
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  • Murphy, F.
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  • Tinant, BernardUCLouvain
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  • Dumont, W.
    Author
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Abstract
The ISMS condensation between allyl silane 3 and ortholactone 13 smoothly leads, after oxidative cleavage and stereoselective reduction, to spiroketal 2b, a model for the subunit present in milbemycin beta(3).
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Marko, I., Declercq, J.-P., Bailey, M., Murphy, F., Tinant, B., Feneaudupont, J., Krief, A., & Dumont, W. (1995). Synthetic Studies Towards Milbemycin Beta(3) - Rapid Construction of a Model Spiroketal Subunit Using the Intramolecular Silyl Modified Sakurai (isms) Methodology. Synlett : accounts and rapid communications in synthetic organic chemistry, 1, 123-126. https://doi.org/10.1055/s-1995-4858 (Original work published 1995)