1-aza-1,3-dienes - Diels-alder Reactions With Alpha,Beta-unsaturated Hydrazones

Serckx-Poncin, Béatrice;Frisque-Hesbain, Anne-Marie;Ghosez, Léon
(1982) Tetrahedron Letters — Vol. 23, n° 32, p. 3261-3264 (1982)

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Authors
  • Serckx-Poncin, BéatriceUCLouvain
    Author
  • Frisque-Hesbain, Anne-MarieUCLouvain
    Author
  • Ghosez, LéonUCLouvain
    Author
Abstract
The Alpha, Beta unsaturated hydrazone reacts regioselectivity with a wide range of dienophiles to give the corresponding [4+2] adducts. Reductive cleavage of the N N bond in the adducts gives tetrahydropyridines.
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Serckx-Poncin, B., Frisque-Hesbain, A.-M., & Ghosez, L. (1982). 1-aza-1,3-dienes - Diels-alder Reactions With Alpha,Beta-unsaturated Hydrazones. Tetrahedron Letters, 23(32), 3261-3264. https://doi.org/10.1016/S0040-4039(00)87586-3 (Original work published 1982)