A hydrogen-bonded organic framework with ultramicroporous channels based on proline and DL-2-phenoxypropionic acid

Steenhaut, Timothy;Li, Xiao;Zhou, Fuli;Robeyns, Koen;Shemchuk, Oleksii;et.al.
(2025) CrystEngComm — Vol. 27, n° 23, p. 3887-3890 (2025)

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Abstract
The cocrystallization of two small, common organic molecules, namely DL-2-phenoxypropionic acid and DL-proline, resulted in the formation of a hydrogen-bonded organic framework with a large unit cell. The obtained solid displays a structure possessing unidimensional ultramicroporous channels, whose functionality was shown by dynamic water vapor sorption and reversible xenon sorption assessed by in situ X-ray powder diffraction.
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Steenhaut, T., Li, X., Zhou, F., Robeyns, K., Leyssens, T., Filinchuk, Y., & Shemchuk, O. (2025). A hydrogen-bonded organic framework with ultramicroporous channels based on proline and DL-2-phenoxypropionic acid. CrystEngComm, 27(23), 3887-3890. https://doi.org/10.1039/d5ce00357a (Original work published 2025)