Polymorphism of copper(I) halide π-complexes: Synthesis and structure of a new modification of [Cu2Cl2(CH2=CH-CH 2)2O]
(2008) Zeitschrift für anorganische und allgemeine Chemie — Vol. 634, n° 9, p. 1587-1590 (2008)
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- Abstract
- A new polymorph of [Cu2Cl2(CH2=CH-CH 2)2O] has been obtained by an alternating-current electrochemical synthesis starting from CuCl2 and triallylphosphite. Diallylether was obtained in statu nascendi via transetherification of triallylphosphite. The structure is monoclinic, space group P21/n, a = 7.6738(7), b = 6.5128(4), c = 18.2689(18) Å, β = 91.644(11)°, V = 912.67(13) Å3 (at 150 K), Z = 4; R1 = 0.0339, wR2 = 0.0822. Flexibility of the organic ligand and weak interactions copper⋯halogen have been identified as the main reasons enabling polymorphism in molecular π-complexes of copper(I). ©2008 Wiley-VCH Verlag GmbH & Co. KGaA.
- Affiliations
ESRF, Grenoble (France) Chimie
Citations
Olijnyk, V. V., Filinchuk, Y., & Lenkivs’ka, T. P. (2008). Polymorphism of copper(I) halide π-complexes: Synthesis and structure of a new modification of [Cu2Cl2(CH2=CH-CH 2)2O]. Zeitschrift für anorganische und allgemeine Chemie, 634(9), 1587-1590. https://doi.org/10.1002/zaac.200800042 (Original work published 2008)