Preparation and characterization of bis(8-quinolinato)tin(II)
(1997) Inorganica Chimica Acta — Vol. 255, n° 1, p. 175-179 (1997)
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- The structure of the complex obtained by reacting tin(II) dichloride dihydrate and oxine (8-hydroxyquinoline) has been characterized by IR, Mossbauer and NMR spectroscopy. The absence of coordinated water molecules was demonstrated by thermogravimetry. The stoichiometry of the complex obtained at pH 6.5 is tin(II)/oxinate in the molar ratio 1:2, as shown by Job's and molar ratio methods. The complex has a lambda(max) = 363 nm in aqueous solution. Its stability was investigated by UV-Vis spectroscopy. The solubility of this complex in different media has been studied by spectrophotometry and its stability constant has been determined.
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Alafandy, M., Willem, R., Mahieu, B., Alturky, M., Gielen, M., Biesemans, M., Legros, F., Camu, F., & Kauffmann, J. (1997). Preparation and characterization of bis(8-quinolinato)tin(II). Inorganica Chimica Acta, 255(1), 175-179. https://doi.org/10.1016/S0020-1693(96)05337-6 (Original work published 1997)