Asymmetric Grignard Addition To Aldehydes - An Example of Inverse Temperature-dependence of Enantiomeric Excess

Marko, Istvan;Chesney, LA.;Hollinshead, DM.
(1994) Tetrahedron: Asymmetry — Vol. 5, n° 4, p. 569-572 (1994)

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Authors
  • Marko, IstvanUCLouvain
    Author
  • Chesney, LA.
    Author
  • Hollinshead, DM.
    Author
Abstract
The addition of organomagnesium derivatives to aldehydes, promoted by chiral diamine 3 shows an inverse correlation between ee and temperature.
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Marko, I., Chesney, LA., & Hollinshead, DM. (1994). Asymmetric Grignard Addition To Aldehydes - An Example of Inverse Temperature-dependence of Enantiomeric Excess. Tetrahedron: Asymmetry, 5(4), 569-572. https://doi.org/10.1016/0957-4166(94)80020-0 (Original work published 1994)