First paramagnetic PdII complex with a PdN4S 2 coordination core

Safin, Damir;Babashkina, M.G.;Garcia, Yann
(2013) Dalton Transactions — Vol. 42, n° 4, p. 902-905 (2013)

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  • Safin, DamirUCLouvain
    Author
  • Babashkina, M.G.UCLouvain
    Author
  • Garcia, Yannorcid-logoUCLouvain
    Author
Abstract
Reaction of the potassium salt of N-thiophosphorylated thiourea 2-PyNHC(S)NHP(S)(OiPr)2 (HL) with PdCl2 in aqueous MeOH leads to the formation of two mononuclear homoleptic complexes [Pd{2-PyNHC(S)NP(S)(OiPr)2-1,5-S,S′}2] ([Pd(L-1,5-S,S′)2]) and [Pd{2-PyNHC(S)NP(S)(OiPr) 2-1,5,7-N,N′,S}2] ([Pd(L-1,5,7-N,N′,S) 2]), while the mechanically induced solid-state reaction of KL and PdCl2 leads to the exclusive formation of [Pd(L-1,5,7-N,N′,S) 2]. The dithiocoordinated desmotrope is square-planar and diamagnetic, while the second desmotrope is unprecedentedly octahedrally configured and paramagnetic. © The Royal Society of Chemistry 2013.
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Safin, D., Babashkina, M. G., & Garcia, Y. (2013). First paramagnetic PdII complex with a PdN4S 2 coordination core. Dalton Transactions, 42(4), 902-905. https://doi.org/10.1039/c2dt32505e (Original work published 2013)