A series of mixed-metal borohydrides
(2009) Angewandte Chemie (International Edition) — Vol. 48, n° 36, p. 6659-6663 (2009)
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- Authors
- Abstract
- Mix and match: A novel series of alkali-metal zinc borohydrides, LiZn 2(BH 4) 5 (see picture), NaZn 2(BH 4) 5, and NaZn(BH 4) 3, with fascinating structures are presented. An interpenetrated network structure, containing a [Zn 2(BH 4) 5] -. ion, is observed for the first time for a borohydride. A three-dimensional framework containing a polymeric [{Zn(BH 4) 3} n] n- ion is also identified. © 2009 Wiley-VCH Verlag GmbH & Co. KCaA.
- Affiliations
ESRF, Grenoble (France) Chimie
Citations
Ravnsbœk, D., Filinchuk, Y., Cerenius, Y., Jakobsen, H. J., Besenbacher, F., Skibsted, J., & Jensen, T. R. (2009). A series of mixed-metal borohydrides. Angewandte Chemie (International Edition), 48(36), 6659-6663. https://doi.org/10.1002/anie.200903030 (Original work published 2009)