Synthesis, infrared, Raman, NMR and Mossbauer studies of some mononuclear inorganic mono and dibasic acid triphenyltin IV derivatives

Diop, CAK;Lahlou, M;Diop, L;Mahieu, Bernard;Russo, U.
(1997) Silicon, Germanium, Tin and Lead Compounds — Vol. 20, n° 10, p. 681-686 (1997)

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Authors
  • Diop, CAK
    Author
  • Lahlou, M
    Author
  • Diop, L
    Author
  • Mahieu, BernardUCLouvain
    Author
  • Russo, U.
    Author
Abstract
Title mononuclear derivatives of general formulae Ph(3)SnA (A=O2PH2, O2PPh2, O2AsMe2, O3SC6H5, O3SC6H4Me-4, O3SC6H3Me2-2,5) and [R4N]Ph3Sn(O(4)A')] (R=Me, Et and A=Cr,C-2 have been synthesized and characterized by elemental analyses, i.r, Raman, Mossbauer and NMR spectroscopies. The spectroscopic results suggest polymeric structures with bridging oxyanions for all the derivatives with distorted (or not) trigonal bipyramidal geometries around the tin centers.
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Diop, C., Lahlou, M., Diop, L., Mahieu, B., & Russo, U. (1997). Synthesis, infrared, Raman, NMR and Mossbauer studies of some mononuclear inorganic mono and dibasic acid triphenyltin IV derivatives. Silicon, Germanium, Tin and Lead Compounds, 20(10), 681-686. https://hdl.handle.net/2078.5/88003 (Original work published 1997)