Hybrid material constructed from Hg(NCS)2and 2,4,6-Tris(2-pyrimidyl)-1,3,5-triazine (TPymT): Coordination of TPymT in a 2,2′-bipyridine-like mode
(2015) European Journal of Inorganic Chemistry — Vol. 2015, n° 3, p. 441-446 (2015)
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- Abstract
- A unique HgII coordination polymer has been synthesized through the reaction of 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT) with a stoichiometric mixture of HgCl2 and NH4NCS, thus leading to the formation of a 1D polymeric heteroleptic hybrid material[{Hg(NCS)2}2TPymT]n (1). Two coordination pockets of TPymT in 1 are each coordinated to two HgII cations in an unprecedented 2,2′-bipyridine-like mode. © 2015 Wiley-VCH Verlag GmbH & Co. KGaA.
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Safin, D. A., Holmberg, R. J., Burgess, K. M. N., Robeyns, K., Bryce, D. L., & Murugesu, M. (2015). Hybrid material constructed from Hg(NCS)2and 2,4,6-Tris(2-pyrimidyl)-1,3,5-triazine (TPymT): Coordination of TPymT in a 2,2′-bipyridine-like mode. European Journal of Inorganic Chemistry, 2015(3), 441-446. https://doi.org/10.1002/ejic.201402832 (Original work published 2015)