Snr(2)(O(2)phph)(2) (R=Me, Bu), Snbu(3)o(2)phph, Me4NO2PHPh center dot 2snph(3)cl And Cy2NH2SnPh2(O(2)phph)(3): Synthesis and Spectroscopic Studies

De Barros, Dinora;Diop, Libasse;Mahieu, Bernard
(2010) Silicon, Germanium, Tin and Lead Compounds — Vol. 33, n° 1-2, p. 83-89 (2010)

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  • De Barros, Dinora
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  • Diop, Libasse
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  • Mahieu, BernardUCLouvain
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Abstract
Five phenylhydrophosphinato organotin(IV) derivatives and adducts have been synthesized and studied by infrared and Mossbauer techniques. The structures suggested on the basis of spectroscopic data are of discrete, infinite or oligomeric types, the phenylhydrophosphinate anion behaving as a bridging bidentate or a monodentate ligand, the environment around the tin centre being trigonal bipyramidal or octahedral.
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De Barros, D., Diop, L., & Mahieu, B. (2010). Snr(2)(O(2)phph)(2) (R=Me, Bu), Snbu(3)o(2)phph, Me4NO2PHPh center dot 2snph(3)cl And Cy2NH2SnPh2(O(2)phph)(3): Synthesis and Spectroscopic Studies. Silicon, Germanium, Tin and Lead Compounds, 33(1-2), 83-89. https://hdl.handle.net/2078.5/81485 (Original work published 2010)