Nonstereospecificity in the Cyclo-additions of Keteneiminium Salts To Olefins - Evidence for a Stepwise Mechanism

Saimoto, Hiroyuki;Houge, Catherine;Frisque-Hesbain, Anne-Marie;Mockel, Anne;Ghosez, Léon
(1983) Tetrahedron Letters — Vol. 24, n° 22, p. 2251-2254 (1983)

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Authors
  • Saimoto, HiroyukiUCLouvain
    Author
  • Houge, CatherineUCLouvain
    Author
  • Frisque-Hesbain, Anne-MarieUCLouvain
    Author
  • Mockel, AnneUCLouvain
    Author
  • Ghosez, LéonUCLouvain
    Author
Abstract
The stereospecificity of the olefin-keteneiminium salt reaction is shown to be dependent on the nitrogen substituents. This is taken as evidence for a stepwise mechanism.
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Saimoto, H., Houge, C., Frisque-Hesbain, A.-M., Mockel, A., & Ghosez, L. (1983). Nonstereospecificity in the Cyclo-additions of Keteneiminium Salts To Olefins - Evidence for a Stepwise Mechanism. Tetrahedron Letters, 24(22), 2251-2254. https://doi.org/10.1016/S0040-4039(00)81896-1 (Original work published 1983)