Towards the synthesis of a metal hamburger complex: The interaction of the PCy2(CH2)3Ph ligand with ruthenium clusters
(2004) Journal of Cluster Science : including nanoclusters and nanoparticles — Vol. 15, n° 3, p. 315-329 (2004)
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- The reactions of [Ru m C(CO) n ] (m = 5, n = 15; 3 m = 6, n = 17; 4) with PCy2(CH2)3Ph afforded mono- and bis-substituted derivatives [Ru5C(CO)14PCy 2 (CH2)3Ph] 13, [Ru5C(CO) 13{PCy2(CH2)3Ph}2] 14, [Ru6C(CO)16PCy2(CH2)3Ph] 15 and [Ru6C(CO)15{PCy2(CH2) 3Ph}2] 16. Compounds 13-16 were characterised spectroscopically and the molecular and crystal structures of compound 13, 13a ([Ru5C(CO)14PPh2(CH2) 3Ph]), 14 and 16 were determined by single crystal X-ray crystallography. Compound [Ru6C(CO)15{PCy 2(CH2)3Ph}2] 16 was subjected to a thermal treatment in dibutylether, however no reaction was observed. © 2004 Plenum Publishing Corporation.
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Johnson, B. F. G., Khimyak, T., Wansel, F. W., Phillips, G., Hermans, S., & Adams, J. R. (2004). Towards the synthesis of a metal hamburger complex: The interaction of the PCy2(CH2)3Ph ligand with ruthenium clusters. Journal of Cluster Science : including nanoclusters and nanoparticles, 15(3), 315-329. https://doi.org/10.1023/B:JOCL.0000041198.96714.4c (Original work published 2004)