The Structure and Solid-state Conformation of (e)-(9r,10r)-9,10-epoxy-17-beta-hydroxy 4a-oxa-a-homo-5,10-8,9-disecoandrost-3-ene-5,8-dione Acetate
(1992) Societes Chimiques Belges. Bulletin — Vol. 101, n° 8, p. 685-688 (1992)
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- Abstract
- the molecular structure of the title compound, a 15-membered 9,10-epoxy-3-en-4-ol lactone, which is an important intermediate in the reaction sequence correlating steroid compounds with prostaglandin-like derivatives, was determined by X-ray analysis. The (E) stereochemistry around the double bond and the trans-(9R,10R)-configuration at the oxirane ring are established.
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Tinant, B., Declercq, J.-P., Bondarenko-Gheorghiu, L., Pavlovic, V., Lorenc, L., & Mihailovic, ML. (1992). The Structure and Solid-state Conformation of (e)-(9r,10r)-9,10-epoxy-17-beta-hydroxy 4a-oxa-a-homo-5,10-8,9-disecoandrost-3-ene-5,8-dione Acetate. Societes Chimiques Belges. Bulletin, 101(8), 685-688. https://doi.org/10.1002/bscb.19921010805 (Original work published 1992)