Reversible photochromism of an N-salicylidene aniline anion

Jacquemin, Pierre-Loïc;Robeyns, Koen;Devillers, Michel;Garcia, Yann
(2014) Chemical Communications — Vol. 50, n° 6, p. 649-651 (2014)

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Authors
  • Jacquemin, Pierre-LoïcUCLouvain
    Author
  • Robeyns, KoenUCLouvain
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  • Devillers, Michelorcid-logoUCLouvain
    Author
  • Garcia, Yannorcid-logoUCLouvain
    Author
Abstract
The first N-salicylidene aniline anion showing reversible solid state thermochromic and photochromic properties is described. The photo-isomerization involves a trans-keto form which is stabilized thanks to the local anion surrounding. This photochromic anion can be used as a guest for the preparation of hybrid materials by insertion into a cationic host matrix. © 2014 The Royal Society of Chemistry.
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Jacquemin, P.-L., Robeyns, K., Devillers, M., & Garcia, Y. (2014). Reversible photochromism of an N-salicylidene aniline anion. Chemical Communications, 50(6), 649-651. https://doi.org/10.1039/c3cc45080e (Original work published 2014)