Evaporation induced micellization of poly(2-oxazoline) multiblock copolymers on surfaces

Fustin, Charles-André;Huang, Haiying;Hoogenboom, Richard;Wiesbrock, Frank;Gohy, Jean-François;et.al.
(2007) Soft Matter — Vol. 3, n° 1, p. 79-82 (2007)

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Abstract
The formation of micelles on surfaces by spin-coating dilute solutions of diblock, triblock, and tetrablock copoly(2-oxazoline)s in a non-selective solvent is demonstrated. The micelles are not preexistent in the initial solution but are formed during the evaporation of the solvent by precipitation of the least-soluble block. The morphology and size of the micelles vary according to the fraction of this block but are not dependent on the block order in the copolymer.
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Fustin, C.-A., Huang, H., Hoogenboom, R., Wiesbrock, F., Jonas, A., Schubert, U. S., & Gohy, J.-F. (2007). Evaporation induced micellization of poly(2-oxazoline) multiblock copolymers on surfaces. Soft Matter, 3(1), 79-82. https://doi.org/10.1039/b611962j (Original work published 2007)