Synthesis and crystal structure of the π copper(I) cyanide complex with N,N′-diallyl thiocarbamide 2CuCN • (C3H 5NH)2CS
(2007) Russian Journal of Coordination Chemistry — Vol. 33, n° 11, p. 809-814 (2007)
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- Abstract
- Crystals of the π copper(I) cyanide complex with N,N′-diallyl thiocarbamide, 2CuCN • (C3H5NH)2CS (I), are synthesized from an aqueous-methanol solution of potassium nitroprusside, diallyl thiocarbamide on a copper electrode using the method of alternating-current electrochemical synthesis. The crystals are monoclinic: space group P21/n, a = 6.9440(5) Å, b = 13.760(1)) Å, c = 12.733(1) Å, β = 97.280(9)°, V = 1206.8(2) Å3, Z = 4, R = 0.0361, R w = 0.0362 for 2836 independent reflections with F ≥ 4σ(F). A unique polymeric structure is built due to the Cu(I)-(C=C) π bond and the bridging function of the thioamide S atom of the ligand molecule and one of the two independent cyano groups. © 2007 Pleiades Publishing, Ltd.
- Affiliations
ESRF, Grenoble (France) Chimie
Citations
Vakulka, A. A., Filinchuk, Y., & Mys’kiv, M. G. (2007). Synthesis and crystal structure of the π copper(I) cyanide complex with N,N′-diallyl thiocarbamide 2CuCN • (C3H 5NH)2CS. Russian Journal of Coordination Chemistry, 33(11), 809-814. https://doi.org/10.1134/S1070328407110048 (Original work published 2007)