Alpha-cyclization of Tertiary-amines .2. Via (2+2) Cycloaddition of Beta-aminoacrylonitriles With Acetylenedicarboxylate

Jiang, SP.;Janousek, Z.;Viehe, HG.
(1993) Societes Chimiques Belges. Bulletin — Vol. 102, n° 10, p. 663-668 (1993)

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  • Jiang, SP.
    Author
  • Janousek, Z.
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  • Viehe, HG.
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Abstract
The reaction of beta-tert.- aminoacrylonitriles 1 a-1 c with dimethyl acetylenedicarboxylate (DMAD) to give pyrrolizidine, indolizidine and pyrroloazepine is described.
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Jiang, SP., Janousek, Z., & Viehe, HG. (1993). Alpha-cyclization of Tertiary-amines .2. Via (2+2) Cycloaddition of Beta-aminoacrylonitriles With Acetylenedicarboxylate. Societes Chimiques Belges. Bulletin, 102(10), 663-668. https://doi.org/10.1002/bscb.19931021007 (Original work published 1993)