Si-29 nuclear magnetic resonance of poly(methylphenyl)silane

Demahieu, AF.;Devaux, Jacques;Dereppe, C.;Baudoux, G;Delhalle, Joseph
(1996) Journal of Polymer Science. Part A, Polymer Chemistry — Vol. 34, n° 5, p. 763-769 (1996)

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Authors
  • Demahieu, AF.
    Author
  • Devaux, JacquesUCLouvain
    Author
  • Dereppe, C.
    Author
  • Baudoux, G
    Author
  • Delhalle, JosephUnamur
    Author
Abstract
A Cl-terminated poly(methylphenyl)silane is synthesized and analyzed by Si-29-NMR spectroscopy. Assignments are proposed for the different peaks observed. A modification of the chemical shifts of the peaks relative to the main chain atoms is observed upon heating. From these experimental results and computational calculations on model compounds, the assignments of the three main peaks to configurationally different Si atoms are confirmed. (C) 1996 John Wiley & Sons, Inc.
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Demahieu, AF., Devaux, J., Dereppe, C., Baudoux, G., & Delhalle, J. (1996). Si-29 nuclear magnetic resonance of poly(methylphenyl)silane. Journal of Polymer Science. Part A, Polymer Chemistry, 34(5), 763-769. https://doi.org/10.1002/(SICI)1099-0518(19960415)34:5<763::AID-POLA6>3.0.CO;2-O (Original work published 1996)