Theoretical condition for transparency in mesoporous layered optical media: application to switching of hygrochromic coatings

Deparis, Olivier;Ghazzal, Mohamed;Simonis, Priscilla;Mouchet, Sébastien;Vigneron, Jean-Pol;et.al.
(2014) Applied Physics Letters — Vol. 104, n° 023704, p. 1-4 (2014)

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Authors
  • Deparis, OlivierUnamur
    Author
  • Ghazzal, MohamedUCLouvain
    Author
  • Simonis, PriscillaUnamur
    Author
  • Mouchet, SébastienUnamur
    Author
  • Author
  • Vigneron, Jean-PolUnamur
    Author
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Abstract
Mesoporous Bragg stacks are able to change color upon infiltration or displacement of liquid compounds inside their porous structure. Reversible switching from transparency to coloration offers additional functionality. Based on Bruggeman's effective medium theory, we derive a transparency master equation, which is valid for bilayers of arbitrary host materials and pore-filling compounds. The transparency condition fixes pore volume fractions such that the effective refractive index is homogenized through the bilayer, hence, through arbitrary layered optical media built from this bilayer. This general concept is applied to the case of switching of hygrochromic coatings made of mesoporous mixed oxide Bragg stacks.
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Citations

Deparis, O., Ghazzal, M., Simonis, P., Mouchet, S., Kebaili, H., de Coninck, J., Gaigneaux, E., & Vigneron, J.-P. (2014). Theoretical condition for transparency in mesoporous layered optical media: application to switching of hygrochromic coatings. Applied Physics Letters, 104(023704), 1-4. https://doi.org/10.1063/1.4862658 (Original work published 2014)