Asymmetric Diels-alder Reactions With Chiral 1-azadienes

Beaudegnies, Renaud;Ghosez, Léon
(1994) Tetrahedron: Asymmetry — Vol. 5, n° 4, p. 557-560 (1994)

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  • Beaudegnies, RenaudUCLouvain
    Author
  • Ghosez, LéonUCLouvain
    Author
Abstract
Chiral 1-azadienes 1 derived from alpha,beta-unsaturated aldehydes and Enders' hydrazines cycloadd to cyclic dienophiles with high facial selectivities. The adducts can be readily converted into enantiomerically pure piperidine derivatives.
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Beaudegnies, R., & Ghosez, L. (1994). Asymmetric Diels-alder Reactions With Chiral 1-azadienes. Tetrahedron: Asymmetry, 5(4), 557-560. https://doi.org/10.1016/0957-4166(94)80017-0 (Original work published 1994)