Proof of the Stereochemistry of Cis-2,5-dibromocyclopentanone

Boelens, M.;Declercq, Jean-Paul;Dekimpe, N.;Keppens, M.
(1994) The Journal of Organic Chemistry — Vol. 59, n° 15, p. 4170-4171 (1994)

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Authors
  • Boelens, M.
    Author
  • Declercq, Jean-PaulUCLouvain
    Author
  • Dekimpe, N.
    Author
  • Keppens, M.
    Author
Abstract
The assignment of the long-standing problem of the stereochemistry of cis-2,5-dibromocyclopentanone has been performed by stereoselective reduction into cis, cis-2,5-dibromocyclopentanol, conversion of the latter alcohol into the 4-nitrobenzoate ester, and following H-1 NMR and X-ray crystallographic-analysis.
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Boelens, M., Declercq, J.-P., Dekimpe, N., & Keppens, M. (1994). Proof of the Stereochemistry of Cis-2,5-dibromocyclopentanone. The Journal of Organic Chemistry, 59(15), 4170-4171. https://doi.org/10.1021/jo00094a030 (Original work published 1994)