The spontaneous reaction of Cu(hfac) (TMVS) Vapor with DuPont Teflon AF1660

Popovici, D;Sacher , E;Meunier, M;Martinu, L;Bertrand, Patrick;et.al.
(1996) 189th Meeting of the electrochemical society, symposium on Metallized Plastics: fundamental and applied aspects V — Location: Los Angeles, USA (1996)

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  • Popovici, DEcole Polytechnique, Montreal, PQ H3C 3A7, Canada
    Author
  • Sacher , EEcole Polytechnique, Montreal, PQ H3C 3A7, Canada
    Author
  • Meunier, MEcole Polytechnique, Montreal, PQ H3C 3A7, Canada
    Author
  • Martinu, LEcole Polytechnique, Montreal, PQ H3C 3A7, Canada
    Author
  • Léonard, DidierUCLouvain
    Author
  • Bertrand, PatrickUCLouvain
    Author
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Abstract
Preliminary X-ray photoelectron spectroscopic (XPS) and time-of-flight secondary ion mass spectroscopic (TOF-SIMS) measurements have confirmed the reaction of Teflon AF1600 with vapors of copper (hexafluoroacetylacetonate) (trimethyl vinyl silane) [C(hfac)(TMVS)], when exposed in the dark. XPS reveals the deposited copper to be in the Cu*II state, while TOF-SIMS has shown the organometallic to have lost its ligands in bonding to the surface.
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Citations

Popovici, D., Sacher, E., Meunier, M., Martinu, L., Léonard, D., & Bertrand, P. (1996). The spontaneous reaction of Cu(hfac) (TMVS) Vapor with DuPont Teflon AF1660. Electrochemical Society. Meeting Abstracts, 96(1), 393. https://hdl.handle.net/2078.5/154112 (Original work published 1996)