Rotaxane-based mechanically linked block copolymers

De Bo, Guillaume;De Winter, Julien;Gerbaux, Pascal;Fustin, Charles-André
(2011) Angewandte Chemie (International Edition) — Vol. 50, n° 39, p. 9093-9096 (2011)

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We just clicked: A convergent approach consisting of two successive copper(I)-catalyzed azide-alkyne cycloaddition "click" reactions leads to a diblock copolymer in which the two blocks are linked by a rotaxane-type mechanical bond (see scheme). Rotaxane formation is templated by a square-planar PdII complex. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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De Bo, G., De Winter, J., Gerbaux, P., & Fustin, C.-A. (2011). Rotaxane-based mechanically linked block copolymers. Angewandte Chemie (International Edition), 50(39), 9093-9096. https://doi.org/10.1002/anie.201103716 (Original work published 2011)