A new supramolecular assembly obtained from the combination of silver(I) cations with a thiophosphorylated cavitand

Bibal, B;Declercq, Jean-Paul;Tinant, Bernard;Dutasta, JP.
(2002) Chemical Communications — n° 5, p. 432-433 (2002)

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  • Bibal, B
    Author
  • Declercq, Jean-PaulUCLouvain
    Author
  • Tinant, BernardUCLouvain
    Author
  • Dutasta, JP.
    Author
Abstract
The new tetra-thiophosphonatocavitand 1 in its iiii configuration extracts quantitatively Ag+ ions from aqueous solutions; the tetranuclear complex [1(2).Ag(4)Pic(4)] was selectively formed and characterized in the solid state by X-ray diffraction which revealed the formation of a new dimeric assembly through Ag+ coordination.
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Bibal, B., Declercq, J.-P., Tinant, B., & Dutasta, JP. (2002). A new supramolecular assembly obtained from the combination of silver(I) cations with a thiophosphorylated cavitand. Chemical Communications, 5, 432-433. https://doi.org/10.1039/b110698h (Original work published 2002)