Control of the radical polymerization by 2,2,15,15-tetramethyl-1-aza-4,7,10,13-tetraoxacyclopentadecan-1-oxyl and its sodium salt

Olive, G;Rozanska, X;Smulders, W;Jacques, Alain;German, A
(2002) Macromolecular Chemistry and Physics — Vol. 203, n° 12, p. 1790-1796 (2002)

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  • Olive, G
    Author
  • Rozanska, X
    Author
  • Smulders, W
    Author
  • Jacques, AlainUCLouvain
    Author
  • German, A
    Author
Abstract
The control of the radical polymerization of styrene by 2,2,15,15-tetramethyl-1-aza-4,7,10,13-tetraoxacyclopentadecan-1-oxyl is reported here in bulk at 90degreesC, 120degreesC and in miniemulsion. Similarly, the control by its sodium complex is reported in bulk at 90degreesC.
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Olive, G., Rozanska, X., Smulders, W., Jacques, A., & German, A. (2002). Control of the radical polymerization by 2,2,15,15-tetramethyl-1-aza-4,7,10,13-tetraoxacyclopentadecan-1-oxyl and its sodium salt. Macromolecular Chemistry and Physics, 203(12), 1790-1796. https://doi.org/10.1002/1521-3935(200208)203:12<1790::AID-MACP1790>3.0.CO;2-F (Original work published 2002)