Magnesium borohydride: Synthesis and crystal structure

Cerný, R.;Filinchuk, Yaroslav;Hagemann, H.;Yvon, K.
(2007) Angewandte Chemie (International Edition) — Vol. 46, n° 30, p. 5765-5767 (2007)

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Abstract
(Figure Presented) Unexpected structural complexity: Well-crystallized Mg(BH4)2 powder is obtained, allowing the structure to be determined from synchrotron X-ray and neutron diffraction data. Mg(BH 4)2 is a novel and remarkably complex three-dimensional framework in which each Mg2+ ion (blue) is tetrahedrally coordinated by four [BH4]- tetrahedra (B red, H gray; see picture). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
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  • ESRF, Grenoble (Frane)Chimie

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Cerný, R., Filinchuk, Y., Hagemann, H., & Yvon, K. (2007). Magnesium borohydride: Synthesis and crystal structure. Angewandte Chemie (International Edition), 46(30), 5765-5767. https://doi.org/10.1002/anie.200700773 (Original work published 2007)