Synthesis, Spectroscopic Characterization and Invitro Antitumor-activity of Di-normal-butyltin and Diethyltin Trimethoxybenzoates - X-ray Structure-analysis of Bis[di-normal-butyl(3,4,5-trimethoxybenzoato)tin] Oxide

Gielen, M.;Meunierpiret, J.;Biesemans, M.;Willem, R.;Elkhloufi, A.
(1992) Applied Organometallic Chemistry — Vol. 6, n° 1, p. 59-67 (1992)

Files

No attached file found for this publication.

Details

Authors
  • Gielen, M.
    Author
  • Meunierpiret, J.
    Author
  • Biesemans, M.
    Author
  • Willem, R.
    Author
  • Elkhloufi, A.
    Author
Abstract
Di-n-butyltin(IV) and diethyltin(IV) 2,3,4-, 2,4,5- and 3,4,5-trimethoxybenzoates [(CH3O)3C6H2COO]2SnR [Type a] and {[CH3O)3C6H2COO]R2Sn}2O [Type b] have been synthesized and characterized spectroscopically. The crystal structure of bis[di-n-butyl(3,4,5-trimethoxybenzoato)tin] oxide has been determined. The triclinic unit cell contains one centrosymmetric dimer; a = 15.919(2) angstrom, b = 11.711(3) angstrom, c = 13.475(1) angstrom, and alpha = 63.63(2)-degrees, beta = 67.49(1)-degrees, gamma = 76.61(2)-degrees. The geometry of the dimer is very similar to that of bis[di-n-butyl(5-methoxysalicylatotin] oxide, with two different types of five-coordinate tin atoms and one central planar Sn2O2 ring.
Affiliations

Citations

  • APA
  • Chicago
  • FWB

Gielen, M., Meunierpiret, J., Biesemans, M., Willem, R., & Elkhloufi, A. (1992). Synthesis, Spectroscopic Characterization and Invitro Antitumor-activity of Di-normal-butyltin and Diethyltin Trimethoxybenzoates - X-ray Structure-analysis of Bis[di-normal-butyl(3,4,5-trimethoxybenzoato)tin] Oxide. Applied Organometallic Chemistry, 6(1), 59-67. https://doi.org/10.1002/aoc.590060108 (Original work published 1992)