Kinetics of the Liquid-phase Esterification of Acrylic-acid With Butanol Catalyzed By Cation-exchange Resin
(1993) Journal of Chemical Technology and Biotechnology — Vol. 58, n° 4, p. 351-355 (1993)
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- Abstract
- Esterification of butyl alcohol with acrylic acid catalysed by Amberlyst-15 cation exchange resin was carried out in a batch reactor in the liquid phase in the temperature range 333 to 364 K and 1 atm. The reaction rate increased with an increase in catalyst concentration and decreased with an increase in water concentration. The rate data were correlated with a kinetic model based on inhibition by water. The apparent activation energy was found to be 59.5 kJ mol-1 for the formation of butyl acrylate.
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Darge, O., & Thyrion, FC. (1993). Kinetics of the Liquid-phase Esterification of Acrylic-acid With Butanol Catalyzed By Cation-exchange Resin. Journal of Chemical Technology and Biotechnology, 58(4), 351-355. https://hdl.handle.net/2078.5/42993 (Original work published 1993)