The molybdenum diphosphate Mo1.3O(P2O7), containing Mo2 and Mo3 clusters
(2003) Journal of Alloys and Compounds — Vol. 360, n° 1-2, p. 81-84 (2003)
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- Abstract
- A novel molybdenum diphosphate, Mo1.3O(P2O 7), was obtained by electrochemical lithium deintercalation. The diphosphate crystallises in space group I2/a with the lattice parameters a = 22.88(1), b = 22.94(2), c = 4.832(1) Å, γ = 90.36°, Z = 8. Its original framework is built up from MoO6 octahedra, P 2O7 groups and also from MoO4, Mo 2O4 and Mo3O8 units containing Mo2 and Mo3 clusters. These polyhedra delimit large octagonal and z-shaped tunnels running along c, in which the inserted cations may be located. © 2003 Elsevier B.V. All rights reserved.
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Lisnyak, V. V., Stus, N. V., Popovich, P., Stratiychuk, D. A., Filinchuk, Y., & Davydov, V. M. (2003). The molybdenum diphosphate Mo1.3O(P2O7), containing Mo2 and Mo3 clusters. Journal of Alloys and Compounds, 360(1-2), 81-84. https://doi.org/10.1016/S0925-8388(03)00208-1 (Original work published 2003)