An allylation-metathesis sequence as a convergent strategy towards enantiopure equivalents of highly functionalized cyclic dienes
(2003) Tetrahedron Letters — Vol. 44, n° 38, p. 7197-7199 (2003)
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- Highly enantioenriched equivalents of cyclic dienes have been readily prepared by asymmetric allylation of unsaturated aldehydes using a chiral allyltitanium reagent, followed by a ring-closing metathesis. The resulting beta-hydroxy allylsilanes react stereoselectively with a wide variety of electrophilic reagents. (C) 2003 Elsevier Ltd. All rights reserved.
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de Fays, L., Adam, J.-M., & Ghosez, L. (2003). An allylation-metathesis sequence as a convergent strategy towards enantiopure equivalents of highly functionalized cyclic dienes. Tetrahedron Letters, 44(38), 7197-7199. https://doi.org/10.1016/S0040-4039(03)01791-X (Original work published 2003)