Preparation and Catalytic Activity of Titanium Pillared Montmorillonite

Delcastillo, HL.;Grange, Paul
(1993) Applied Catalysis A: General — Vol. 103, n° 1, p. 23-34 (1993)

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Authors
  • Delcastillo, HL.
    Author
  • Grange, PaulUCLouvain
    Author
Abstract
Thermally stable titanium pillared montmorillonite has been prepared by the intercalation of four different titanium alkoxides. X-ray diffraction, BET, chemical analysis, themogravimetric analysis, differential thermal analysis, temperature-programmed desorption of ammonia and IR spectra of samples allow the determination of the structure. The catalysts prepared from Ti (OEt)4 present the most interesting structural properties after calcination. The titanium pillared montmorillonite with pillars of ca. 12 angstrom shows high activity in the dehydration of 1-butanol. The selectivity of the catalyst is directly related to its acidic properties.
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Delcastillo, HL., & Grange, P. (1993). Preparation and Catalytic Activity of Titanium Pillared Montmorillonite. Applied Catalysis A: General, 103(1), 23-34. https://doi.org/10.1016/0926-860X(93)85170-T (Original work published 1993)