Preparation and characterization of WOX-CeO2 catalysts

Alifanti, M;Visinescu, CM;Parvulescu, VI;Grange, Paul;Poncelet, Georges
(2002) 8th International Symposium on Scientific Bases for the Preparation of Heterogeneous Catalysts — Location: UNIV CATHOLIQUE LOUVAIN, LOUVAIN LA NEUVE (Belgium) (9.September.2002)

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  • Alifanti, M
    Author
  • Visinescu, CM
    Author
  • Parvulescu, VI
    Author
  • Grange, PaulUCLouvain
    Author
  • Poncelet, GeorgesUCLouvain
    Author
Abstract
Tungsten-ceria catalysts were prepared by co-precipitation and impregnation techniques looking for the effect of the tungsten loading and calcination temperature. The catalysts were characterized by adsorption-desorption isotherms of N-2 at 77 K, in-situ XRD, NH3-DRIFT, Raman spectroscopy, and XPS. It was found that the preparation method influences the texture of the catalyst, the tungsten loading, the dispersion of the WO, domains which correspond to a different interaction with ceria, and the temperature of formation of the Ce-2(WO4)(3) species which seem to be responsible for the strong Lewis/Bronsted acid sites.
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Alifanti, M., Visinescu, C., Parvulescu, V., Grange, P., & Poncelet, G. (2002). Preparation and characterization of WOX-CeO2 catalysts. Studies in Surface Science and Catalysis, 143, 337-344. https://doi.org/10.1016/S0167-2991(00)80673-4 (Original work published 2002)