Crystal structure and physical properties of the new linear chain compound [Cu(1,2-bis(tetrazol-1-yl)ethane)3](ClO4)2
(2001) Inorganica Chimica Acta — Vol. 326, n° 1, p. 101-105 (2001)
Files
pdfdocument.pdf
Restricted Access - Adobe PDF
- 153.37 KB
Details
- Authors
- Abstract
- The synthesis and crystal structure of a novel one-dimensional Cu(II) compound [Cu(1,2-bis(tetrazol-1-yl)ethane)3](ClO4)2 are described. The single-crystal X-ray structure determination was carried out at 298 K. The molecular structure consists of a linear chain in which the Cu(II) ions are linked by three N4,N4' coordinating bis(tetrazole) ligands in syn conformation. The Cu(II) ions are in a Jahn–Teller distorted octahedral environment (Cu(1)-N(11)=2.034(2) A- , Cu(1)-N(21)=2.041(2) A- and Cu(1)-N(31)= 2.391(2) A- ). The Cu···Cu separations are 7.420(3) A.
- Affiliations
University of Mainz (Germany) Inorganic and Analytical Chemistry
Citations
van Koningsbruggen, P. J., Garcia, Y., Bravic, G., Chasseau, D., & Kahn, O. (2001). Crystal structure and physical properties of the new linear chain compound [Cu(1,2-bis(tetrazol-1-yl)ethane)3](ClO4)2. Inorganica Chimica Acta, 326(1), 101-105. https://doi.org/10.1016/S0020-1693(01)00645-4 (Original work published 2001)