Improved Enantioselectivity in the Inverse Electron Demand Diels-alder Cycloadditions of 3-carbomethoxy-2-pyrone Catalyzed By Chiral Ytterbium Complexes

Marko, Istvan;Evans, GR.;Declercq, JR.;Feneau-Dupont, J.;Tinant, Bernard
(1994) Societes Chimiques Belges. Bulletin — Vol. 103, n° 5-6, p. 295-297 (1994)

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  • Marko, IstvanUCLouvain
    Author
  • Evans, GR.
    Author
  • Declercq, JR.
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  • Feneau-Dupont, J.UCLouvain
    Author
  • Tinant, BernardUCLouvain
    Author
Abstract
When catalysed by the Kobayashi: Yb(OTf)3-Binol complex, vinyl ethers and vinyl sulphides undergo highly enantioselective IEDDA reactions with 3-carbomethoxy-2-pyrone.
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Marko, I., Evans, GR., Declercq, JR., Feneau-Dupont, J., & Tinant, B. (1994). Improved Enantioselectivity in the Inverse Electron Demand Diels-alder Cycloadditions of 3-carbomethoxy-2-pyrone Catalyzed By Chiral Ytterbium Complexes. Societes Chimiques Belges. Bulletin, 103(5-6), 295-297. https://doi.org/10.1002/bscb.19941030516 (Original work published 1994)