Base-Catalysed Intramolecular Hydroamination of Vinyl Sulfides

Quinet, Coralie;Sampoux, Laetitia;Marko, Istvan
(2009) European Journal of Organic Chemistry — n° 11, p. 1806-1811 (2009)

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  • Quinet, CoralieUCLouvain
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  • Sampoux, LaetitiaUCLouvain
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  • Marko, IstvanUCLouvain
    Author
Abstract
Small amounts of n-butyllithium catalyse the highly efficient hydroamination of a large variety of vinyl sulfides. This novel methodology offers an easy access to a wide range of nitrogen heterocycles, including simple pyrrolidines and piperidines, as well as more complex bicyclic compounds. Subsequent transformations of the sulfur group led to the formation of functionalised alkaloid-like substructures. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
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Quinet, C., Sampoux, L., & Marko, I. (2009). Base-Catalysed Intramolecular Hydroamination of Vinyl Sulfides. European Journal of Organic Chemistry, 11, 1806-1811. https://doi.org/10.1002/ejoc.200900009 (Original work published 2009)