Melt-Polymerization of TEMPO Methacrylates with Nano Carbons Enables Superior Battery Materials

Vlad, Alexandru;Rolland, Julien;Hauffman, Guillaume;Ernould, Bruno;Gohy, Jean-François
(2015) ChemSusChem (Print) : chemistry & sustainability, energy & materials — Vol. 8, n° 10, p. 1692-1696 (2015)

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A solvent-free, melt polymerization process of a 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) precursor for rechargeable organic radical batteries is proposed. In situ carbon incorporation in the melted monomer phase yields a nanoscale homogenous polymer composite. Superior battery performances including higher power and cycling stability are attained by using the melt-polymerization method.
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Vlad, A., Rolland, J., Hauffman, G., Ernould, B., & Gohy, J.-F. (2015). Melt-Polymerization of TEMPO Methacrylates with Nano Carbons Enables Superior Battery Materials. ChemSusChem (Print) : chemistry & sustainability, energy & materials, 8(10), 1692-1696. https://doi.org/10.1002/cssc.201500246 (Original work published 2015)